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A dangerous good is any Solid , Liquid , or Gas that can harm people, other living Organism s, property, or the environment. An equivalent term, used almost exclusively in the United States, is ''hazardous material'' (hazmat). Dangerous goods may be Radioactive , Flammable , Explosive , Toxic , Corrosive , Biohazardous , an Oxidizer , an Asphyxiant , a Pathogen , an Allergen , or may have other characteristics that render it hazardous in specific circumstances.

Mitigating the risks associated with hazardous materials may require the application of safety precautions during their Transport , use, Storage and Disposal . Most countries regulate hazardous materials by law, and they are subject to several international treaties as well.

Persons who handle dangerous goods will often wear protective equipment, and metropolitan Fire Department s often have a response team specifically trained to deal with accidents and spills. These teams train with different organizations at a variety of specialized locations. Some of the most well-known in the U.S. and Canada include the California Specialized Training Institute, the Texas A&M TEEX Academy, Signet North America, the Justice Institute of British Columbia, and the U.S. National Fire Academy.

Laws and regulations on the use and handling of hazardous materials may differ depending on the activity and status of the material. For example one set of requirements may apply to their use in the workplace while a different requirements may apply to spill response, sale for consumer use, or transportation. Most countries regulate some aspect of hazardous materials.

The most widely applied regulatory scheme is that for the transportation of dangerous goods. The Committee of Experts on the Transport of Dangerous Goods of the has developed regulations for air transport of hazardous materials that are based upon the UN Model but modified to accommodate unique aspects of air transport. Individual airline and governmental requirements are incorporated with this by the International Air Transport Association to produce the widely used IATA Dangerous Goods Regulations . Similarly, the International Maritime Organization has developed the IMO Dangerous Goods Regulations for transportation on the high seas. Many individual nations have also structured their dangerous goods transportation regulations to harmonize with the UN Model in organization as well as in specific requirements.

Dangerous goods are divided into classes on the basis of the specific chemical characteristics producing the risk.

Note: The graphics and text in this article representing the dangerous goods safety marks are derived from the United Nations-based system of identifying dangerous goods. Not all countries use precisely the same graphics (label, placard and/or text information) in their national regulations. Some use graphic symbols, but without English wording or with similar wording in their national language. Refer to the Dangerous Goods Transportation Regulations of the country of interest.

For example, see the [http://www.tc.gc.ca/tdg/Documents/tp11504e.htm Dangerous Goods Safety Marks] in the Canadian [http://www.tc.gc.ca/tdg/clear/tofc.htm Transportation of Dangerous Goods Regulations].

The statement above applies equally to all the Dangerous Goods classes discussed in this article.


CLASSIFICATION AND LABELLING SUMMARY TABLES


Class 1: Explosives


Information on this graphic changes depending on which, "Division" of explosive is shipped.

Explosive Dangerous Goods have compatibility group letters assigned to facilitate segregation during transport. The letters used range from A to S excluding the letters I, M, O, P, Q and R. The example above shows an explosive with a compatibility group "A" (shown as 1.1A). The actual letter shown would depend on the specific properties of the substance being transported.

For example, the [http://www.tc.gc.ca/tdg/clear/part2.htm#app2 Canadian Transportation of Dangerous Goods Regulations] provides a description of compatibility groups.

  • 1.1 Explosives with a mass explosion hazard

  • --- Ex: TNT , Dynamite , Nitroglycerine .

  • 1.2 Explosives with a severe projection hazard.

  • 1.3 Explosives with a fire, blast or projection hazard but not a mass explosion hazard.

  • 1.4 Minor fire or projection hazard (includes ammunition and most consumer fireworks).

  • 1.5 An insensitive substance with a mass explosion hazard (explosion similar to 1.1)

  • 1.6 Extremely insensitive articles.


The United States Department Of Transportation (DOT) regulates hazmat transportation within the territory of the US.

:1.1 — Explosives with a mass explosion hazard. ( Nitroglycerin / Dynamite )
:1.2 — Explosives with a blast/projection hazard.
:1.3 — Explosives with a minor blast hazard. (rocket propellant, display fireworks)
:1.4 — Explosives with a major fire hazard. (consumer Fireworks , ammunition)
:1.5 — Blasting agents.
:1.6 — Extremely insensitive explosives.


Class 2: Gases

Gases which are compressed, liquefied or dissolved under pressure as detailed below. Some gases have subsidiary risk classes; poisonous or corrosive.


  • 2.1 Flammable gas

  • --- Gases which ignite on contact with an ignition source.


  • -- Ex: Acetylene , Hydrogen .


  • 2.2 Non-Flammable Gases

  • --- Gases which are neither flammable nor poisonous.


  • -- Ex: Nitrogen , Neon .

  • Includes the cryogenic gases/liquids (temperatures of below -100 °C) used for cryopreservation and rocket fuels.





Class 3: Flammable liquids


Flammable liquids included in Class 3 are included in one of the following packing groups:

  • Packing Group I, if they have an initial boiling point of 35°C or less at an absolute pressure of 101.3 kPa and any Flash Point ;

  • --- Ex: Diethyl Ether , Carbon Disulfide .

  • Packing Group II, if they have an initial boiling point greater than 35°C at an absolute pressure of 101.3 kPa and a flash point less than 23°C; or

  • --- Ex: Gasoline (petrol) , Acetone .

  • Packing Group III, if the criteria for inclusion in Packing Group I or II are not met.

  • --- Ex: Kerosene , Diesel .


Note: For further details, check the Dangerous Goods Transportation Regulations of the country of interest.


Class 4: Flammable solids


  • 4.1 Flammable solids which are easily ignited and readily combustible.

  • --- Ex: Nitrocellulose , Magnesium , safety or strike-anywhere Match es.




  • 4.3 Substances which emit a flammable gas when wet or react violently with water.

  • --- Ex: Sodium , Calcium , Potassium .



Class 5: Oxidizing Agents & Organic Peroxides





Class 6: Toxic and Infectious Substances



  • 6.2 Biohazardous substances.

  • --- Ex: Virus cultures, Pathology specimens, used intravenous needles.

  • Divided into two categories by the WHO: Cat. A (infectious) and Cat. B (samples).



Class 7: Radioactive Substances


  • Radioactive substances comprise substances or a combination of substances which emit ionizing radiation.

  • --- Ex: Uranium , Plutonium .

  • Class 8: Corrosive Substances



Solids or liquids that can dissolve organic tissue or severely corrode certain metals.


Class 9: Miscellaneous Dangerous Substances




OTHER HAZARDOUS MATERIALS LABELS (CHIP)


Xn, harmful, '''Xi''', Irritant


T, toxic


C, corrosive


O, oxidizing


F, flammable


E, explosive


N, environmental hazard


AUSTRALIA

Uses the standard international UN numbers with a few slightly different signs on the back, front and sides of vehicles carrying hazardous substances. Uses the same "HAZCHEM" as the UK HAZCHEM Code to provide advisory information to emergency services personnel in the event of an emergency situation.


CANADA

Transport of hazardous materials in Canada is under the jurisdiction of Transport Canada . Hazard classifications are also based upon the UN Model.


EUROPE

The European Union has passed numerous Directives and regulations to avoid the dissemination and restrict the usage of hazardous substances, the most famous being the Restriction Of Hazardous Substances Directive and the REACH directive. There are also long standing European treaties such as ADR and RID that regulate the transportation of hazardous materials by road, rail, river and inland waterways, following the guide of the UN Model Regulation.


UNITED STATES


Due to the increased threat of Terrorism in the early 21st Century , funding for greater HAZMAT-handling capabilities was increased throughout the United States , in recognition of the fact that flammable, poisonous, explosive, or radioactive substances in particular could make attractive weapons for terrorist attacks.

The United States Department Of Transportation (DOT) regulates hazmat transportation within the territory of the US. The regulations are found in [http://hazmat.dot.gov/regs/rules.htm 49 CFR] (Title 49 of the Code of Federal Regulations).

The U.S. Occupational Safety And Health Administration (OSHA) regulates the handling of hazardous materials in the workplace as well as response to hazardous materials-related incidents, most notably through HAZWOPER (HAZ-ardous W-aste OP-erations and E-mergency R-esponse) regulations found at 29 CFR 1910.120.

The Environmental Protection Agency regulates hazardous materials as they may impact the community and environment, including specific regulations for environmental cleanup and for handling and disposal of waste hazardous materials.

The Consumer Product Safety Commission regulates hazardous materials that may be used in products sold for household and other consumer uses.


Hazard classes for materials in transport

Following the UN Model, the DOT divides regulated hazardous materials into nine classes, some of which are further divided into divisions. Hazardous materials in transportation must be placarded. Some materials must always be placarded, others may only require placarding in certain circumstances.

Trailers of goods in transport are usually marked with a four digit UN ( United Nations ) number. This number can be referenced by first responders ( Firefighter s, Police Officer s, and Ambulance personnel) who can find information about the material in the '' Emergency Response Guidebook ''.


Fixed facilities

Different standards usually apply for handling and marking HAZMATs at fixed facilities, including NFPA 704 diamond markings (a consensus standard often adopted by local governmental jurisdictions), OSHA regulations requiring chemical safety information for employees, and CPSC requirements requiring informative labeling for the public, as well as wearing Hazmat Suit s when handling hazardous materials.


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