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PROBLEMS WITH HARD WATER

Waters that have been in contact with limestone and other sediments tend to acquire dissolved ions, mainly of calcium Ca2+ and magnesium Mg2+. The positive electrical charges of these ions are balanced by the presence of anions (negative ions), of which bicarbonate HCO3– and carbonate CO32– are the most important. These ions have their origins in carbon dioxide which is present in all waters exposed to the atmosphere and also in groundwaters.

These "hardness ions" cause two major kinds of problems:

  • The metal ions react with soaps and calcium sensitive detergents), hindering their ability to lather properly and forming an unsightly precipitate— the familiar scum or "bathtub ring". Presence of "hardness ions" also inhibits the cleaning effect of detergent formulations.

  • More seriously, calcium and magnesium carbonates tend to precipitate out as adherent solids on the surfaces of pipes and especially on the hot heat exchanger surfaces of boilers. The resulting scale buildup can restrict water flow in pipes. In boilers, the deposits act as thermal insulation that impedes the flow of heat into the water; this not only reduces heating efficiency, but allows the metal to overheat which, in a pressurized system, can lead to catastrophic failure.


Conventional water-softening devices intended for household use depend on an Ion-exchange Resin in which "hardness" ions trade places with sodium that are electrostatically bound to the Cationic functional groups of the polymeric resin . A class of minerals known as Zeolites also exhibit ion-exchange properties and were widely used in earlier water softeners.


HOW IT WORKS

The water to be treated passes through a bed of the resin;
  • negatively-charged resins absorb and bind metal ions, which are always positively charged. These resins initially contain sodium ions, which are displaced into the water stream by the more strongly-attracted di-positive ions of magnesium and calcium.


As the water passes through both kinds of resin, the hardness ions replace the sodium which are released into the water. For most purposes, the low levels of salt in the treated water are innocuous. However because of the increase in sodium concentration, water softened in this way is not suitable for regular consumption.


REGENERATON


As these resins become converted to their Ca2+ form they gradually lose their effectiveness and must be regenerated. This is accomplished by passing a concentrated brine solution though them, causing the above processes to be reversed. Herein lies one of the drawbacks of this system: most of the salt employed in the regeneration process gets flushed out of the system and may be released into the soil or drainage— something that can have damaging consequences to the environment, especially in arid regions. For this reason, many jurisdications prohibit such release, and require users to dispose of the spent brine at an approved site or to use a commercial service company.


SEE ALSO




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