Information About

Hexamethylene Triperoxide Diamine




  IUPAC Name 3,4,8,9,12,13-hexaoxa-1,6-<br>diazabicyclo {Link without Title} tetradecane
  chemical Formula C <sub>6</sub> H <sub>12</sub> N <sub>2</sub> O <sub>6</sub>
  molecular Weight 208169 G / Mol
  shock Sensitivity High
  friction Sensitivity High
  density 088 g/cm<sup>3</sup>
  explosive Velocity ~4500 M/s
  RE Factor
  melting Point Decomposes at 75 °C
  boiling Point N/A
  appearance
  CAS Number 283-66-9
  PubChem 61101
  SMILES C1N2COOCN(COO1)COOC2


Hexamethylene triperoxide diamine, or '''HMTD''' is a

High Explosive
Organic Chemical compound, first synthesised in in 1885 by Legler1. The theorised structure lent itself well to acting as an initiating, or Primary Explosive . While still quite sensitive to shock and friction, it was relatively stable compared to other initiating explosives of the time, such as Mercury Fulminate , and proved to be relatively inexpensive and easy to synthesise. As such, it was quickly taken up as a primary explosive in mining applications2. However, it has since been superceded by even more stable compounds such as Tetryl .

Despite no longer being used in any official application, it remains a fairly popular Home-made Explosive and has been used in a large number of Suicide Bombing s throughout the world, including the 7 July 2005 London Bombings 3.

The easiest synthesis of HMTD involves unrestricted ingredients including Hydrogen Peroxide , Citric Acid or dilute Sulfuric Acid as a Catalyst and Hexamine Fuel Tablets , which are available from camping supply stores or with military rations. Like other organic peroxides such as Acetone Peroxide , HMTD is an unstable compound that is sensitive to shock, friction, and heat. HMTD degrades too quickly for modern commercial and industrial applications, becoming useless in a matter of weeks. The compound is frequently suggested as a homemade explosive formulation.


HOW-TO

fortunecity.com/hmtd.html


REFERENCES

# Legler, L. ''Ber''. 1885, ''18'', 3343-3351.
# Taylor, C. A.; Rinkenbach, W. H. ''Army Ordnance'' 1924. ''5'', 463-466
# "London bombers used everyday materials" Reuters , August 4 , 2005 , retrieved April 16 , 2006