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Fehling's Solution




Fehling's solution is always made just prior to the test. Two equal volumes of solutions are mixed:
# 69.28 grams Copper(II) Sulfate pentahydrate and fill to 1 litre of solution with distilled water
# 346 grams Rochelle Salt (potassium sodium tartrate tetrahydrate) and 120 grams Sodium Hydroxide and fill to 1 litre of solution with distilled water

The cupric ion is Complexed with the tartrate ion. Contact with an aldehyde group reduces it to a cuprous ion, which then precipitates as red Cu2O ( Copper(I) Oxide ).

Fehling's solution is nowadays often replaced by Benedict's Solution .


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